\(\newcommand{\footnotename}{footnote}\)
\(\def \LWRfootnote {1}\)
\(\newcommand {\footnote }[2][\LWRfootnote ]{{}^{\mathrm {#1}}}\)
\(\newcommand {\footnotemark }[1][\LWRfootnote ]{{}^{\mathrm {#1}}}\)
\(\newcommand \ensuremath [1]{#1}\)
\(\newcommand {\LWRframebox }[2][]{\fbox {#2}} \newcommand {\framebox }[1][]{\LWRframebox } \)
\(\newcommand {\setlength }[2]{}\)
\(\newcommand {\addtolength }[2]{}\)
\(\newcommand {\setcounter }[2]{}\)
\(\newcommand {\addtocounter }[2]{}\)
\(\newcommand {\cline }[1]{}\)
\(\newcommand {\directlua }[1]{\text {(directlua)}}\)
\(\newcommand {\luatexdirectlua }[1]{\text {(directlua)}}\)
\(\newcommand {\protect }{}\)
\(\def \LWRabsorbnumber #1 {}\)
\(\def \LWRabsorbquotenumber "#1 {}\)
\(\def \mathchar {\ifnextchar "\LWRabsorbquotenumber \LWRabsorbnumber }\)
\(\def \mathcode #1={\mathchar }\)
\(\let \delcode \mathcode \)
\(\let \delimiter \mathchar \)
\(\let \LWRref \ref \)
\(\renewcommand {\ref }{\ifstar \LWRref \LWRref }\)
\(\newcommand {\intertext }[1]{\text {#1}\notag \\}\)
\(\newcommand {\mathllap }[2][]{{#1#2}}\)
\(\newcommand {\mathrlap }[2][]{{#1#2}}\)
\(\newcommand {\mathclap }[2][]{{#1#2}}\)
\(\newcommand {\mathmbox }[1]{#1}\)
\(\newcommand {\clap }[1]{#1}\)
\(\newcommand {\LWRmathmakebox }[2][]{#2}\)
\(\newcommand {\mathmakebox }[1][]{\LWRmathmakebox }\)
\(\newcommand {\cramped }[2][]{{#1#2}}\)
\(\newcommand {\crampedllap }[2][]{{#1#2}}\)
\(\newcommand {\crampedrlap }[2][]{{#1#2}}\)
\(\newcommand {\crampedclap }[2][]{{#1#2}}\)
\(\newenvironment {crampedsubarray}[1]{}{}\)
\(\newcommand {\crampedsubstack }{}\)
\(\newcommand {\smashoperator }[2][]{#2\limits }\)
\(\newcommand {\adjustlimits }{}\)
\(\newcommand {\SwapAboveDisplaySkip }{}\)
\(\require {extpfeil}\)
\(\Newextarrow \xleftrightarrow {10,10}{0x2194}\)
\(\Newextarrow \xLeftarrow {10,10}{0x21d0}\)
\(\Newextarrow \xhookleftarrow {10,10}{0x21a9}\)
\(\Newextarrow \xmapsto {10,10}{0x21a6}\)
\(\Newextarrow \xRightarrow {10,10}{0x21d2}\)
\(\Newextarrow \xLeftrightarrow {10,10}{0x21d4}\)
\(\Newextarrow \xhookrightarrow {10,10}{0x21aa}\)
\(\Newextarrow \xrightharpoondown {10,10}{0x21c1}\)
\(\Newextarrow \xleftharpoondown {10,10}{0x21bd}\)
\(\Newextarrow \xrightleftharpoons {10,10}{0x21cc}\)
\(\Newextarrow \xrightharpoonup {10,10}{0x21c0}\)
\(\Newextarrow \xleftharpoonup {10,10}{0x21bc}\)
\(\Newextarrow \xleftrightharpoons {10,10}{0x21cb}\)
\(\newcommand {\LWRdounderbracket }[3]{\underset {#3}{\underline {#1}}}\)
\(\newcommand {\LWRunderbracket }[2][]{\LWRdounderbracket {#2}}\)
\(\newcommand {\underbracket }[1][]{\LWRunderbracket }\)
\(\newcommand {\LWRdooverbracket }[3]{\overset {#3}{\overline {#1}}}\)
\(\newcommand {\LWRoverbracket }[2][]{\LWRdooverbracket {#2}}\)
\(\newcommand {\overbracket }[1][]{\LWRoverbracket }\)
\(\newcommand {\LATEXunderbrace }[1]{\underbrace {#1}}\)
\(\newcommand {\LATEXoverbrace }[1]{\overbrace {#1}}\)
\(\newenvironment {matrix*}[1][]{\begin {matrix}}{\end {matrix}}\)
\(\newenvironment {pmatrix*}[1][]{\begin {pmatrix}}{\end {pmatrix}}\)
\(\newenvironment {bmatrix*}[1][]{\begin {bmatrix}}{\end {bmatrix}}\)
\(\newenvironment {Bmatrix*}[1][]{\begin {Bmatrix}}{\end {Bmatrix}}\)
\(\newenvironment {vmatrix*}[1][]{\begin {vmatrix}}{\end {vmatrix}}\)
\(\newenvironment {Vmatrix*}[1][]{\begin {Vmatrix}}{\end {Vmatrix}}\)
\(\newenvironment {smallmatrix*}[1][]{\begin {matrix}}{\end {matrix}}\)
\(\newenvironment {psmallmatrix*}[1][]{\begin {pmatrix}}{\end {pmatrix}}\)
\(\newenvironment {bsmallmatrix*}[1][]{\begin {bmatrix}}{\end {bmatrix}}\)
\(\newenvironment {Bsmallmatrix*}[1][]{\begin {Bmatrix}}{\end {Bmatrix}}\)
\(\newenvironment {vsmallmatrix*}[1][]{\begin {vmatrix}}{\end {vmatrix}}\)
\(\newenvironment {Vsmallmatrix*}[1][]{\begin {Vmatrix}}{\end {Vmatrix}}\)
\(\newenvironment {psmallmatrix}[1][]{\begin {pmatrix}}{\end {pmatrix}}\)
\(\newenvironment {bsmallmatrix}[1][]{\begin {bmatrix}}{\end {bmatrix}}\)
\(\newenvironment {Bsmallmatrix}[1][]{\begin {Bmatrix}}{\end {Bmatrix}}\)
\(\newenvironment {vsmallmatrix}[1][]{\begin {vmatrix}}{\end {vmatrix}}\)
\(\newenvironment {Vsmallmatrix}[1][]{\begin {Vmatrix}}{\end {Vmatrix}}\)
\(\newcommand {\LWRmultlined }[1][]{\begin {multline*}}\)
\(\newenvironment {multlined}[1][]{\LWRmultlined }{\end {multline*}}\)
\(\let \LWRorigshoveleft \shoveleft \)
\(\renewcommand {\shoveleft }[1][]{\LWRorigshoveleft }\)
\(\let \LWRorigshoveright \shoveright \)
\(\renewcommand {\shoveright }[1][]{\LWRorigshoveright }\)
\(\newenvironment {dcases}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {dcases*}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {rcases}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {rcases*}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {drcases}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {drcases*}{\begin {cases}}{\end {cases}}\)
\(\newenvironment {cases*}{\begin {cases}}{\end {cases}}\)
\(\newcommand {\MoveEqLeft }[1][]{}\)
\(\def \LWRAboxed #1!|!{\fbox {\(#1\)}&\fbox {\(#2\)}} \newcommand {\Aboxed }[1]{\LWRAboxed #1&&!|!} \)
\( \newcommand {\LWRABLines }[1][\Updownarrow ]{#1 \notag \\}\newcommand {\ArrowBetweenLines }{\ifstar \LWRABLines \LWRABLines } \)
\(\newcommand {\shortintertext }[1]{\text {#1}\notag \\}\)
\(\newcommand {\vdotswithin }[1]{\hspace {.5em}\vdots }\)
\(\newcommand {\LWRshortvdotswithinstar }[1]{\vdots \hspace {.5em} & \\}\)
\(\newcommand {\LWRshortvdotswithinnostar }[1]{& \hspace {.5em}\vdots \\}\)
\(\newcommand {\shortvdotswithin }{\ifstar \LWRshortvdotswithinstar \LWRshortvdotswithinnostar }\)
\(\newcommand {\MTFlushSpaceAbove }{}\)
\(\newcommand {\MTFlushSpaceBelow }{\\}\)
\(\newcommand \lparen {(}\)
\(\newcommand \rparen {)}\)
\(\newcommand {\ordinarycolon }{:}\)
\(\newcommand {\vcentcolon }{\mathrel {\mathop \ordinarycolon }}\)
\(\newcommand \dblcolon {\vcentcolon \vcentcolon }\)
\(\newcommand \coloneqq {\vcentcolon =}\)
\(\newcommand \Coloneqq {\dblcolon =}\)
\(\newcommand \coloneq {\vcentcolon {-}}\)
\(\newcommand \Coloneq {\dblcolon {-}}\)
\(\newcommand \eqqcolon {=\vcentcolon }\)
\(\newcommand \Eqqcolon {=\dblcolon }\)
\(\newcommand \eqcolon {\mathrel {-}\vcentcolon }\)
\(\newcommand \Eqcolon {\mathrel {-}\dblcolon }\)
\(\newcommand \colonapprox {\vcentcolon \approx }\)
\(\newcommand \Colonapprox {\dblcolon \approx }\)
\(\newcommand \colonsim {\vcentcolon \sim }\)
\(\newcommand \Colonsim {\dblcolon \sim }\)
\(\newcommand {\nuparrow }{\mathrel {\cancel {\uparrow }}}\)
\(\newcommand {\ndownarrow }{\mathrel {\cancel {\downarrow }}}\)
\(\newcommand {\bigtimes }{\mathop {\Large \times }\limits }\)
\(\newcommand {\prescript }[3]{{}^{#1}_{#2}#3}\)
\(\newenvironment {lgathered}{\begin {gathered}}{\end {gathered}}\)
\(\newenvironment {rgathered}{\begin {gathered}}{\end {gathered}}\)
\(\newcommand {\splitfrac }[2]{{}^{#1}_{#2}}\)
\(\let \splitdfrac \splitfrac \)
\(\newcommand {\LWRoverlaysymbols }[2]{\mathord {\smash {\mathop {#2\strut }\limits ^{\smash {\lower 3ex{#1}}}}\strut }}\)
\(\newcommand{\alphaup}{\unicode{x03B1}}\)
\(\newcommand{\betaup}{\unicode{x03B2}}\)
\(\newcommand{\gammaup}{\unicode{x03B3}}\)
\(\newcommand{\digammaup}{\unicode{x03DD}}\)
\(\newcommand{\deltaup}{\unicode{x03B4}}\)
\(\newcommand{\epsilonup}{\unicode{x03F5}}\)
\(\newcommand{\varepsilonup}{\unicode{x03B5}}\)
\(\newcommand{\zetaup}{\unicode{x03B6}}\)
\(\newcommand{\etaup}{\unicode{x03B7}}\)
\(\newcommand{\thetaup}{\unicode{x03B8}}\)
\(\newcommand{\varthetaup}{\unicode{x03D1}}\)
\(\newcommand{\iotaup}{\unicode{x03B9}}\)
\(\newcommand{\kappaup}{\unicode{x03BA}}\)
\(\newcommand{\varkappaup}{\unicode{x03F0}}\)
\(\newcommand{\lambdaup}{\unicode{x03BB}}\)
\(\newcommand{\muup}{\unicode{x03BC}}\)
\(\newcommand{\nuup}{\unicode{x03BD}}\)
\(\newcommand{\xiup}{\unicode{x03BE}}\)
\(\newcommand{\omicronup}{\unicode{x03BF}}\)
\(\newcommand{\piup}{\unicode{x03C0}}\)
\(\newcommand{\varpiup}{\unicode{x03D6}}\)
\(\newcommand{\rhoup}{\unicode{x03C1}}\)
\(\newcommand{\varrhoup}{\unicode{x03F1}}\)
\(\newcommand{\sigmaup}{\unicode{x03C3}}\)
\(\newcommand{\varsigmaup}{\unicode{x03C2}}\)
\(\newcommand{\tauup}{\unicode{x03C4}}\)
\(\newcommand{\upsilonup}{\unicode{x03C5}}\)
\(\newcommand{\phiup}{\unicode{x03D5}}\)
\(\newcommand{\varphiup}{\unicode{x03C6}}\)
\(\newcommand{\chiup}{\unicode{x03C7}}\)
\(\newcommand{\psiup}{\unicode{x03C8}}\)
\(\newcommand{\omegaup}{\unicode{x03C9}}\)
\(\newcommand{\Alphaup}{\unicode{x0391}}\)
\(\newcommand{\Betaup}{\unicode{x0392}}\)
\(\newcommand{\Gammaup}{\unicode{x0393}}\)
\(\newcommand{\Digammaup}{\unicode{x03DC}}\)
\(\newcommand{\Deltaup}{\unicode{x0394}}\)
\(\newcommand{\Epsilonup}{\unicode{x0395}}\)
\(\newcommand{\Zetaup}{\unicode{x0396}}\)
\(\newcommand{\Etaup}{\unicode{x0397}}\)
\(\newcommand{\Thetaup}{\unicode{x0398}}\)
\(\newcommand{\Varthetaup}{\unicode{x03F4}}\)
\(\newcommand{\Iotaup}{\unicode{x0399}}\)
\(\newcommand{\Kappaup}{\unicode{x039A}}\)
\(\newcommand{\Lambdaup}{\unicode{x039B}}\)
\(\newcommand{\Muup}{\unicode{x039C}}\)
\(\newcommand{\Nuup}{\unicode{x039D}}\)
\(\newcommand{\Xiup}{\unicode{x039E}}\)
\(\newcommand{\Omicronup}{\unicode{x039F}}\)
\(\newcommand{\Piup}{\unicode{x03A0}}\)
\(\newcommand{\Varpiup}{\unicode{x03D6}}\)
\(\newcommand{\Rhoup}{\unicode{x03A1}}\)
\(\newcommand{\Sigmaup}{\unicode{x03A3}}\)
\(\newcommand{\Tauup}{\unicode{x03A4}}\)
\(\newcommand{\Upsilonup}{\unicode{x03A5}}\)
\(\newcommand{\Phiup}{\unicode{x03A6}}\)
\(\newcommand{\Chiup}{\unicode{x03A7}}\)
\(\newcommand{\Psiup}{\unicode{x03A8}}\)
\(\newcommand{\Omegaup}{\unicode{x03A9}}\)
\(\newcommand{\alphait}{\unicode{x1D6FC}}\)
\(\newcommand{\betait}{\unicode{x1D6FD}}\)
\(\newcommand{\gammait}{\unicode{x1D6FE}}\)
\(\newcommand{\digammait}{\mathit{\unicode{x03DD}}}\)
\(\newcommand{\deltait}{\unicode{x1D6FF}}\)
\(\newcommand{\epsilonit}{\unicode{x1D716}}\)
\(\newcommand{\varepsilonit}{\unicode{x1D700}}\)
\(\newcommand{\zetait}{\unicode{x1D701}}\)
\(\newcommand{\etait}{\unicode{x1D702}}\)
\(\newcommand{\thetait}{\unicode{x1D703}}\)
\(\newcommand{\varthetait}{\unicode{x1D717}}\)
\(\newcommand{\iotait}{\unicode{x1D704}}\)
\(\newcommand{\kappait}{\unicode{x1D705}}\)
\(\newcommand{\varkappait}{\unicode{x1D718}}\)
\(\newcommand{\lambdait}{\unicode{x1D706}}\)
\(\newcommand{\muit}{\unicode{x1D707}}\)
\(\newcommand{\nuit}{\unicode{x1D708}}\)
\(\newcommand{\xiit}{\unicode{x1D709}}\)
\(\newcommand{\omicronit}{\unicode{x1D70A}}\)
\(\newcommand{\piit}{\unicode{x1D70B}}\)
\(\newcommand{\varpiit}{\unicode{x1D71B}}\)
\(\newcommand{\rhoit}{\unicode{x1D70C}}\)
\(\newcommand{\varrhoit}{\unicode{x1D71A}}\)
\(\newcommand{\sigmait}{\unicode{x1D70E}}\)
\(\newcommand{\varsigmait}{\unicode{x1D70D}}\)
\(\newcommand{\tauit}{\unicode{x1D70F}}\)
\(\newcommand{\upsilonit}{\unicode{x1D710}}\)
\(\newcommand{\phiit}{\unicode{x1D719}}\)
\(\newcommand{\varphiit}{\unicode{x1D711}}\)
\(\newcommand{\chiit}{\unicode{x1D712}}\)
\(\newcommand{\psiit}{\unicode{x1D713}}\)
\(\newcommand{\omegait}{\unicode{x1D714}}\)
\(\newcommand{\Alphait}{\unicode{x1D6E2}}\)
\(\newcommand{\Betait}{\unicode{x1D6E3}}\)
\(\newcommand{\Gammait}{\unicode{x1D6E4}}\)
\(\newcommand{\Digammait}{\mathit{\unicode{x03DC}}}\)
\(\newcommand{\Deltait}{\unicode{x1D6E5}}\)
\(\newcommand{\Epsilonit}{\unicode{x1D6E6}}\)
\(\newcommand{\Zetait}{\unicode{x1D6E7}}\)
\(\newcommand{\Etait}{\unicode{x1D6E8}}\)
\(\newcommand{\Thetait}{\unicode{x1D6E9}}\)
\(\newcommand{\Varthetait}{\unicode{x1D6F3}}\)
\(\newcommand{\Iotait}{\unicode{x1D6EA}}\)
\(\newcommand{\Kappait}{\unicode{x1D6EB}}\)
\(\newcommand{\Lambdait}{\unicode{x1D6EC}}\)
\(\newcommand{\Muit}{\unicode{x1D6ED}}\)
\(\newcommand{\Nuit}{\unicode{x1D6EE}}\)
\(\newcommand{\Xiit}{\unicode{x1D6EF}}\)
\(\newcommand{\Omicronit}{\unicode{x1D6F0}}\)
\(\newcommand{\Piit}{\unicode{x1D6F1}}\)
\(\newcommand{\Rhoit}{\unicode{x1D6F2}}\)
\(\newcommand{\Sigmait}{\unicode{x1D6F4}}\)
\(\newcommand{\Tauit}{\unicode{x1D6F5}}\)
\(\newcommand{\Upsilonit}{\unicode{x1D6F6}}\)
\(\newcommand{\Phiit}{\unicode{x1D6F7}}\)
\(\newcommand{\Chiit}{\unicode{x1D6F8}}\)
\(\newcommand{\Psiit}{\unicode{x1D6F9}}\)
\(\newcommand{\Omegait}{\unicode{x1D6FA}}\)
\(\let \digammaup \Digammaup \)
\(\renewcommand {\digammait }{\mathit {\digammaup }}\)
\(\newcommand {\smallin }{\unicode {x220A}}\)
\(\newcommand {\smallowns }{\unicode {x220D}}\)
\(\newcommand {\notsmallin }{\LWRoverlaysymbols {/}{\unicode {x220A}}}\)
\(\newcommand {\notsmallowns }{\LWRoverlaysymbols {/}{\unicode {x220D}}}\)
\(\newcommand {\rightangle }{\unicode {x221F}}\)
\(\newcommand {\intclockwise }{\unicode {x2231}}\)
\(\newcommand {\ointclockwise }{\unicode {x2232}}\)
\(\newcommand {\ointctrclockwise }{\unicode {x2233}}\)
\(\newcommand {\oiint }{\unicode {x222F}}\)
\(\newcommand {\oiiint }{\unicode {x2230}}\)
\(\newcommand {\ddag }{\unicode {x2021}}\)
\(\newcommand {\P }{\unicode {x00B6}}\)
\(\newcommand {\copyright }{\unicode {x00A9}}\)
\(\newcommand {\dag }{\unicode {x2020}}\)
\(\newcommand {\pounds }{\unicode {x00A3}}\)
\(\newcommand {\iddots }{\unicode {x22F0}}\)
\(\newcommand {\utimes }{\overline {\times }}\)
\(\newcommand {\dtimes }{\underline {\times }}\)
\(\newcommand {\udtimes }{\overline {\underline {\times }}}\)
\(\newcommand {\leftwave }{\left \{}\)
\(\newcommand {\rightwave }{\right \}}\)
\(\newcommand {\toprule }[1][]{\hline }\)
\(\let \midrule \toprule \)
\(\let \bottomrule \toprule \)
\(\newcommand {\cmidrule }[2][]{}\)
\(\newcommand {\morecmidrules }{}\)
\(\newcommand {\specialrule }[3]{\hline }\)
\(\newcommand {\addlinespace }[1][]{}\)
\(\newcommand {\LWRsubmultirow }[2][]{#2}\)
\(\newcommand {\LWRmultirow }[2][]{\LWRsubmultirow }\)
\(\newcommand {\multirow }[2][]{\LWRmultirow }\)
\(\newcommand {\mrowcell }{}\)
\(\newcommand {\mcolrowcell }{}\)
\(\newcommand {\STneed }[1]{}\)
\( \newcommand {\multicolumn }[3]{#3}\)
\(\newcommand {\tothe }[1]{^{#1}}\)
\(\newcommand {\raiseto }[2]{{#2}^{#1}}\)
\(\newcommand {\ang }[2][]{(\mathrm {#2})\degree }\)
\(\newcommand {\num }[2][]{\mathrm {#2}}\)
\(\newcommand {\si }[2][]{\mathrm {#2}}\)
\(\newcommand {\LWRSI }[2][]{\mathrm {#1\LWRSInumber \,#2}}\)
\(\newcommand {\SI }[2][]{\def \LWRSInumber {#2}\LWRSI }\)
\(\newcommand {\numlist }[2][]{\mathrm {#2}}\)
\(\newcommand {\numrange }[3][]{\mathrm {#2\,\unicode {x2013}\,#3}}\)
\(\newcommand {\SIlist }[3][]{\mathrm {#2\,#3}}\)
\(\newcommand {\SIrange }[4][]{\mathrm {#2\,#4\,\unicode {x2013}\,#3\,#4}}\)
\(\newcommand {\tablenum }[2][]{\mathrm {#2}}\)
\(\newcommand {\ampere }{\mathrm {A}}\)
\(\newcommand {\candela }{\mathrm {cd}}\)
\(\newcommand {\kelvin }{\mathrm {K}}\)
\(\newcommand {\kilogram }{\mathrm {kg}}\)
\(\newcommand {\metre }{\mathrm {m}}\)
\(\newcommand {\mole }{\mathrm {mol}}\)
\(\newcommand {\second }{\mathrm {s}}\)
\(\newcommand {\becquerel }{\mathrm {Bq}}\)
\(\newcommand {\degreeCelsius }{\unicode {x2103}}\)
\(\newcommand {\coulomb }{\mathrm {C}}\)
\(\newcommand {\farad }{\mathrm {F}}\)
\(\newcommand {\gray }{\mathrm {Gy}}\)
\(\newcommand {\hertz }{\mathrm {Hz}}\)
\(\newcommand {\henry }{\mathrm {H}}\)
\(\newcommand {\joule }{\mathrm {J}}\)
\(\newcommand {\katal }{\mathrm {kat}}\)
\(\newcommand {\lumen }{\mathrm {lm}}\)
\(\newcommand {\lux }{\mathrm {lx}}\)
\(\newcommand {\newton }{\mathrm {N}}\)
\(\newcommand {\ohm }{\mathrm {\Omega }}\)
\(\newcommand {\pascal }{\mathrm {Pa}}\)
\(\newcommand {\radian }{\mathrm {rad}}\)
\(\newcommand {\siemens }{\mathrm {S}}\)
\(\newcommand {\sievert }{\mathrm {Sv}}\)
\(\newcommand {\steradian }{\mathrm {sr}}\)
\(\newcommand {\tesla }{\mathrm {T}}\)
\(\newcommand {\volt }{\mathrm {V}}\)
\(\newcommand {\watt }{\mathrm {W}}\)
\(\newcommand {\weber }{\mathrm {Wb}}\)
\(\newcommand {\day }{\mathrm {d}}\)
\(\newcommand {\degree }{\mathrm {^\circ }}\)
\(\newcommand {\hectare }{\mathrm {ha}}\)
\(\newcommand {\hour }{\mathrm {h}}\)
\(\newcommand {\litre }{\mathrm {l}}\)
\(\newcommand {\liter }{\mathrm {L}}\)
\(\newcommand {\arcminute }{^\prime }\)
\(\newcommand {\minute }{\mathrm {min}}\)
\(\newcommand {\arcsecond }{^{\prime \prime }}\)
\(\newcommand {\tonne }{\mathrm {t}}\)
\(\newcommand {\astronomicalunit }{au}\)
\(\newcommand {\atomicmassunit }{u}\)
\(\newcommand {\bohr }{\mathit {a}_0}\)
\(\newcommand {\clight }{\mathit {c}_0}\)
\(\newcommand {\dalton }{\mathrm {D}_\mathrm {a}}\)
\(\newcommand {\electronmass }{\mathit {m}_{\mathrm {e}}}\)
\(\newcommand {\electronvolt }{\mathrm {eV}}\)
\(\newcommand {\elementarycharge }{\mathit {e}}\)
\(\newcommand {\hartree }{\mathit {E}_{\mathrm {h}}}\)
\(\newcommand {\planckbar }{\mathit {\unicode {x210F}}}\)
\(\newcommand {\angstrom }{\mathrm {\unicode {x212B}}}\)
\(\let \LWRorigbar \bar \)
\(\newcommand {\bar }{\mathrm {bar}}\)
\(\newcommand {\barn }{\mathrm {b}}\)
\(\newcommand {\bel }{\mathrm {B}}\)
\(\newcommand {\decibel }{\mathrm {dB}}\)
\(\newcommand {\knot }{\mathrm {kn}}\)
\(\newcommand {\mmHg }{\mathrm {mmHg}}\)
\(\newcommand {\nauticalmile }{\mathrm {M}}\)
\(\newcommand {\neper }{\mathrm {Np}}\)
\(\newcommand {\yocto }{\mathrm {y}}\)
\(\newcommand {\zepto }{\mathrm {z}}\)
\(\newcommand {\atto }{\mathrm {a}}\)
\(\newcommand {\femto }{\mathrm {f}}\)
\(\newcommand {\pico }{\mathrm {p}}\)
\(\newcommand {\nano }{\mathrm {n}}\)
\(\newcommand {\micro }{\mathrm {\unicode {x00B5}}}\)
\(\newcommand {\milli }{\mathrm {m}}\)
\(\newcommand {\centi }{\mathrm {c}}\)
\(\newcommand {\deci }{\mathrm {d}}\)
\(\newcommand {\deca }{\mathrm {da}}\)
\(\newcommand {\hecto }{\mathrm {h}}\)
\(\newcommand {\kilo }{\mathrm {k}}\)
\(\newcommand {\mega }{\mathrm {M}}\)
\(\newcommand {\giga }{\mathrm {G}}\)
\(\newcommand {\tera }{\mathrm {T}}\)
\(\newcommand {\peta }{\mathrm {P}}\)
\(\newcommand {\exa }{\mathrm {E}}\)
\(\newcommand {\zetta }{\mathrm {Z}}\)
\(\newcommand {\yotta }{\mathrm {Y}}\)
\(\newcommand {\percent }{\mathrm {\%}}\)
\(\newcommand {\meter }{\mathrm {m}}\)
\(\newcommand {\metre }{\mathrm {m}}\)
\(\newcommand {\gram }{\mathrm {g}}\)
\(\newcommand {\kg }{\kilo \gram }\)
\(\newcommand {\of }[1]{_{\mathrm {#1}}}\)
\(\newcommand {\squared }{^2}\)
\(\newcommand {\square }[1]{\mathrm {#1}^2}\)
\(\newcommand {\cubed }{^3}\)
\(\newcommand {\cubic }[1]{\mathrm {#1}^3}\)
\(\newcommand {\per }{/}\)
\(\newcommand {\celsius }{\unicode {x2103}}\)
\(\newcommand {\fg }{\femto \gram }\)
\(\newcommand {\pg }{\pico \gram }\)
\(\newcommand {\ng }{\nano \gram }\)
\(\newcommand {\ug }{\micro \gram }\)
\(\newcommand {\mg }{\milli \gram }\)
\(\newcommand {\g }{\gram }\)
\(\newcommand {\kg }{\kilo \gram }\)
\(\newcommand {\amu }{\mathrm {u}}\)
\(\newcommand {\nm }{\nano \metre }\)
\(\newcommand {\um }{\micro \metre }\)
\(\newcommand {\mm }{\milli \metre }\)
\(\newcommand {\cm }{\centi \metre }\)
\(\newcommand {\dm }{\deci \metre }\)
\(\newcommand {\m }{\metre }\)
\(\newcommand {\km }{\kilo \metre }\)
\(\newcommand {\as }{\atto \second }\)
\(\newcommand {\fs }{\femto \second }\)
\(\newcommand {\ps }{\pico \second }\)
\(\newcommand {\ns }{\nano \second }\)
\(\newcommand {\us }{\micro \second }\)
\(\newcommand {\ms }{\milli \second }\)
\(\newcommand {\s }{\second }\)
\(\newcommand {\fmol }{\femto \mol }\)
\(\newcommand {\pmol }{\pico \mol }\)
\(\newcommand {\nmol }{\nano \mol }\)
\(\newcommand {\umol }{\micro \mol }\)
\(\newcommand {\mmol }{\milli \mol }\)
\(\newcommand {\mol }{\mol }\)
\(\newcommand {\kmol }{\kilo \mol }\)
\(\newcommand {\pA }{\pico \ampere }\)
\(\newcommand {\nA }{\nano \ampere }\)
\(\newcommand {\uA }{\micro \ampere }\)
\(\newcommand {\mA }{\milli \ampere }\)
\(\newcommand {\A }{\ampere }\)
\(\newcommand {\kA }{\kilo \ampere }\)
\(\newcommand {\ul }{\micro \litre }\)
\(\newcommand {\ml }{\milli \litre }\)
\(\newcommand {\l }{\litre }\)
\(\newcommand {\hl }{\hecto \litre }\)
\(\newcommand {\uL }{\micro \liter }\)
\(\newcommand {\mL }{\milli \liter }\)
\(\newcommand {\L }{\liter }\)
\(\newcommand {\hL }{\hecto \liter }\)
\(\newcommand {\mHz }{\milli \hertz }\)
\(\newcommand {\Hz }{\hertz }\)
\(\newcommand {\kHz }{\kilo \hertz }\)
\(\newcommand {\MHz }{\mega \hertz }\)
\(\newcommand {\GHz }{\giga \hertz }\)
\(\newcommand {\THz }{\tera \hertz }\)
\(\newcommand {\mN }{\milli \newton }\)
\(\newcommand {\N }{\newton }\)
\(\newcommand {\kN }{\kilo \newton }\)
\(\newcommand {\MN }{\mega \newton }\)
\(\newcommand {\Pa }{\pascal }\)
\(\newcommand {\kPa }{\kilo \pascal }\)
\(\newcommand {\MPa }{\mega \pascal }\)
\(\newcommand {\GPa }{\giga \pascal }\)
\(\newcommand {\mohm }{\milli \ohm }\)
\(\newcommand {\kohm }{\kilo \ohm }\)
\(\newcommand {\Mohm }{\mega \ohm }\)
\(\newcommand {\pV }{\pico \volt }\)
\(\newcommand {\nV }{\nano \volt }\)
\(\newcommand {\uV }{\micro \volt }\)
\(\newcommand {\mV }{\milli \volt }\)
\(\newcommand {\V }{\volt }\)
\(\newcommand {\kV }{\kilo \volt }\)
\(\newcommand {\W }{\watt }\)
\(\newcommand {\uW }{\micro \watt }\)
\(\newcommand {\mW }{\milli \watt }\)
\(\newcommand {\kW }{\kilo \watt }\)
\(\newcommand {\MW }{\mega \watt }\)
\(\newcommand {\GW }{\giga \watt }\)
\(\newcommand {\J }{\joule }\)
\(\newcommand {\uJ }{\micro \joule }\)
\(\newcommand {\mJ }{\milli \joule }\)
\(\newcommand {\kJ }{\kilo \joule }\)
\(\newcommand {\eV }{\electronvolt }\)
\(\newcommand {\meV }{\milli \electronvolt }\)
\(\newcommand {\keV }{\kilo \electronvolt }\)
\(\newcommand {\MeV }{\mega \electronvolt }\)
\(\newcommand {\GeV }{\giga \electronvolt }\)
\(\newcommand {\TeV }{\tera \electronvolt }\)
\(\newcommand {\kWh }{\kilo \watt \hour }\)
\(\newcommand {\F }{\farad }\)
\(\newcommand {\fF }{\femto \farad }\)
\(\newcommand {\pF }{\pico \farad }\)
\(\newcommand {\K }{\mathrm {K}}\)
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Aufbau nach Elementen
Auf bau der Erde nach Elementen: nach Atom-Prozent besteht die gesamte Erde nur aus sechs Elementen \(\ge \SI {1}{\percent }\), nämlich (50 %), (16 %), (16 %), (14 %), (2 %), (1 %)
Auf bau der kontinentalen Kruste nach Elementen: in der kontinentalen Kruste sieht die Situation anders aus, nämlich (63 %), (23 %), (6 %), (2 %), (2 %), (2 %), (1 %), (1 %)
Element-Anreicherungen in der kontinentalen Kruste: viele für die Biosphäre wichtige Elemente haben sich in der kontinentalen Kruste massiv angereichert, darunter , , , , , , , andere Elemente sind im Vergleich zur Gesamterde ungefähr gleich stark vertreten, darunter , , , , , nur kommt deutlich seltener in der kontinentalen Kruste vor
Differentiation
treibende Kräfte der Evolution: treibende Kraft inorganischer Evolution ist chemische Differentiation, d. h. die Aufteilung eines ursprünglich homogenen Gemisches nach Elementen,
für organische Evolution ist zusätzlich Plattentektonik wichtig
Magmendifferentiation: durch fraktionierte Kristallisation im offenen System findet Magmendifferentiation statt
trockene partielle Aufschmelzung von Mantelgestein: Aufschmelzung von Mantelgestein findet immer nur in Teilschmelzen statt, da die für vollständige Schmelzen benötigte Temperatur auf
der Erde zu niedrig ist (es gibt höchstens 35 %-ige Teilschmelzen)
Silikate: Silikate sind Polymere, die aus Tetraedern der Form aufgebaut sind (Siliziumatom in der Mitte), durch zunehmende chemische Differentiation (Voraussetzung dafür: Gesteinsschmelzen) entstehen immer längere Ketten und Moleküle, bei
100 % vernetzten -Tetraedern erhält man Quarz ()
Erdkruste, Erdmantel und Erdkern
Steinplaneten entwickeln hoch differenzierte Kruste: in der Erdkruste gibt es viel , , , , und Silikate, der obere Erdmantel besteht hauptsächlich aus Silikaten (, und Metalle), im unteren Erdmantel gibt es Oxide von Eisen und Magnesium (, usw.), der Erdkern besteht aus Eisen
Eisenkern: entstand in den ersten 33 Millionen Jahren, besteht aus äußerem Kern (dünnflüssiger als Wasser) und innerem Kern (fest), starkes Magnetfeld durch Turbulenzen
Erdmantel: eigene radiogene Wärmeproduktion aus , , , Kühlung von außen erzeugt Konvektion, Konvektion treibt Plattentektonik an und bildet Hotspots
Erdkruste: ozeanische Kruste (Dichte 3,0 g/cm3) entsteht im Scheitel von Konvektionszellen und wird im Mantel recycelt, dabei nimmt sie Wasser mit, welches sich im darüberliegenden
Mantel löst und Magmen bildet, so entsteht kontinentale Kruste
(Dichte 2,7 g/cm3 bis 2,8 g/cm3)
Atmosphäre: enthält hauptsächlich , , , , (Anteil : 390 ppm = 0,039 %)
Plattentektonik
Frühzeit (4,0 Ga bis 2,5 Ga): heiße ozeanische Lithosphäre schwimmt oben, Stapelung von Kruste und Mantelspänen, wässrige Schmelzen erzeugen
granitähnliche Magmen, Gebirge nicht höher als 2,5 km, keine Plattentektonik, da Wärmefluss zu groß (ozeanische Kruste zu heiß), archaische Grünstein-Gürtel
Plattentektonik-Zeit (seit 2,5 Ga): kältere und weniger hydratisierte Kruste, Basalt wird zu Eklogit, daher tiefreichende Subduktion (da Eklogit dichter ist), wässrige Schmelzen erzeugen
granitähnliche Magmen, Nettowachstum der Kontinente, Gebirge bis 10 km, heutige Ozeane und Kontinente
Plattentektonik-Fenster: bestimmtes Zeitfenster, in dem Plattentektonik stattfinden kann, Mars, Merkur und Mond haben das Fenster vor langer Zeit schnell durchlaufen, da sie aufgrund ihrer kleinen Größe zu
schnell ausgekühlt sind, die Venus war zwar längere Zeit im Fenster, aber ist seit ca. 1 Ga außerhalb, die Erde befindet sich als einziger Planet im Sonnensystem noch innerhalb des Fensters
treibende Kräfte: treibende Kraft der Plattentektonik ist die Mantelkonvektion, treibende Kraft von Klimaveränderungen ist die Plattentektonik
Plattentektonik und Klima: driftende und wachsende Kontinente führen zu einer wechselnden Verteilung von Land und Meer und wechselnden Strömungs- und Verwitterungsmustern, die zwei stabilen
globalen Klimazustände des Treibhausklimas und des akzentuierten Klimas (mit vereisten Polkappen) können durch Plattentektonik erreicht werden, äquatorparallele Kontinent-Barrieren verhinden
Nord-Süd-Zirkulation und führen zu globaler Erwärmung, Superkontinente oder Kontinente an den Polen führen zu globaler Abkühlung, die ständig wechselnden
Umweltbedingungen liefern Evolutionsanreize
Atmosphäre
Uratmosphäre: enthielt keinen Sauerstoff, sondern , , , , , , (Blausäure, wichtig für Bildung von Leben, aber flüchtig), also mehr Treibhausgase als heute, aggressive Verwitterung und rasche Mineralisierung der Ozeane sind Voraussetzungen
für die Entstehung von Leben
Energieausstoß der Sonne: Sonne steigert Energieausstoß um 10 %/Ga, Oberflächentemperatur der Erde vor 3,8 Ga war wahrscheinlich ca. 40 °C (ohne Treibhausgase
wäre sie gleich −19 °C gewesen), wichtig, dass es nicht zu viel und nicht zu wenig Treibhausgase gibt, eine weitere Temperatursenkung ist nur möglich, wenn entnommen und hinzugefügt wird
Fotosynthese: , Fotosynthese-Leistung steigt mit Energieausstoß der Sonne, Senkung des Treibhauseffekts, selbstregelndes System, das den steigenden Energieausstoß der Sonne über mindestens 5 Milliarden Jahre hinweg
kompensiert